Oxygen and nitrogen-functionalized porous carbon particles derived from hazelnut shells for the efficient catalytic hydrogen production reaction

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dc.authorid0000-0003-1052-5903en_US
dc.contributor.authorSaka, Cafer
dc.contributor.authorBalbay, Asım
dc.date.accessioned2021-05-26T10:59:16Z
dc.date.available2021-05-26T10:59:16Z
dc.date.issued2021en_US
dc.departmentMTÖ Üniversitesi, Arapgir Meslek Yüksekokulu, Motorlu Araçlar ve Ulaştırma Teknolojileri Bölümüen_US
dc.description.abstractDue to their low cost and high availability, interest in biomass materials in catalytic studies is increasing. It is possible to increase the catalytic activities by the development of metal-free catalysts obtained by adding different atoms to carbon materials. Here, oxygen (O) and nitrogen (N) doped metal-free carbon catalysts (N-AC-N) were synthesized using activated carbon (AC) obtained from hazelnut shells by KOH activation. These metal-free catalysts were used successfully for the first time in the NaBH4 methanolysis reaction (NaBH4-MR). The structural and physical-chemical properties of the metal-free catalysts obtained were analysed by XRD (X-ray diffraction), elemental analysis (CHNS), FT-IR (Fourier transform infrared spectroscopy), SEM (scanning electron microscopy), and nitrogen adsorption surface analyses. N and O doped metal-free catalyst showed very good catalytic performance against NaBH4-MR. The hydrogen production rate (HGR) with 10 mg metal-free catalyst at 30 °C and the activation energy(Ea) of the reaction were calculated as 16250 mL min?1 g?1 and 11.45 kJ mol?1, respectively. At the same time, with favourable reusability results, this metal-free catalyst is a promising candidate for the hydrogen(H2) generation system.en_US
dc.identifier.citationSaka, Cafer, and Asım Balbay. 2021. "Oxygen and Nitrogen-Functionalized Porous Carbon Particles Derived from Hazelnut Shells for the Efficient Catalytic Hydrogen Production Reaction". Biomass and Bioenergy. 149.en_US
dc.identifier.doi10.1016/j.biombioe.2021.106072
dc.identifier.endpage9en_US
dc.identifier.issn0961-9534en_US
dc.identifier.scopus2-s2.0-85104972278en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage1en_US
dc.identifier.urihttps://doi.org/10.1016/j.biombioe.2021.106072
dc.identifier.urihttps://hdl.handle.net/20.500.12899/149
dc.identifier.volume149en_US
dc.identifier.wosWOS:000663083900010en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorBalbay, Asım
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofBiomass and Bioenergyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectOxygen and Nitrogenen_US
dc.subjectCatalysten_US
dc.subjectOxygen and Nitrogenen_US
dc.subjectSodium Borohydride Methanolysisen_US
dc.titleOxygen and nitrogen-functionalized porous carbon particles derived from hazelnut shells for the efficient catalytic hydrogen production reactionen_US
dc.typeArticleen_US

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