A study on the optoelectronic parameters of 4-chloromethyl-7-hydroxy coumarin in various solvents and concentrations
Yükleniyor...
Tarih
2021
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Türkiye Kimya Derneği
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
A coumarin derivative, namely 4-chloromethyl-7-hydroxy coumarin (CMEHC), was synthesized in order to test the concentration and solvent effect on its optical properties. The spectral characterization of this compound was accomplished by FTIR and 1H-NMR techniques. The UV absorption spectra of CMEHC compound in various solvents (THF, DMSO, DMF) were recorded with a UV–VIS spectrophotometer. The optical parameters such as maximum peak position, absorption band edge, and direct allowed bandgap were reported for these solvents and also various concentrations. The lowest direct allowed bandgap was obtained with THF. The absorbance spectra of CMEHC compound were dominant at the near ultraviolet region. The refractive index values were compared with each other using Moss, Ravindra, Herve-Vandamme, Reddy and Kumar-Singh relations.
Açıklama
1Department of Chemistry, Faculty of Science and Arts, Adiyaman University, Adiyaman/Turkey
2Department of Engineering Basic Sciences, Faculty of Engineering and Natural Sciences, Malatya Turgut
Özal University, Malatya, Turkey
3Department of Pharm. Chemistry, Pharmacy Faculty, Adiyaman University, Adiyaman/Turkey
Anahtar Kelimeler
Coumarin derivative, Optoelectronic parameters, concentration and solvent effect, Absorption band edge, Optical band gap, Refractive index
Kaynak
Journal of the Turkish Chemical Society Section A: Chemistry
WoS Q Değeri
Scopus Q Değeri
Q4
Cilt
8
Sayı
1