Effects of solvents on photonic and fluorescence properties of PtOEP phosphorescent material: Experimental and computational analysis

https://doi.org/10.1016/j.molliq.2020.113865Get rights and content

Highlights

Photonic and fluorescence properties were investigated with different techniques.

Many electronic and optoelectronic parameters have been obtained.

Theoretical and experimental photonic and fluorescence properties were compared.

Maximum absorbances for experimental and theoretical calculations are quite similar.

Abstract

The effects of different solvents (chloroform, tetrahydrofuran, toluene, methanol, acetone and chlorobenzene) on photonic and fluorescence properties of the PtOEP organic phosphorescent material were investigated with experimental and advanced computational techniques. Many parameters such as angle of incidence/refraction, contrast, optical conductance, electrical conductance, peak absorbance, peak emission, stokes shift, fluorescence quantum yield and sensitivity have been obtained. Theoretical and experimental photonic and fluorescence properties of the PtOEP material for different solvents have been compared. It was found that maximum absorbances for experimental and theoretical calculations are quite similar at a value of around 389 (nm) and depending on the solvents used here they slightly shifted to larger wavelength.

Keywords

Organic phosphorescent materials
PtOEP
Theoretical quantum mechanical method
Photonic
Fluorescence quantum yield
Sensitivity
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